项目经历：
1.过渡金属催化醚氧原子α位C(sp3)–F键形成反应研究，国家自然科学基金项目(U1504210), 2016.1-2018.12，主持
2.钌催化导向基协助的芳烃远程硒化反应研究，国家自然科学基金项目(21801007), 2019.01-2021.12，主持
3.喹啉衍生物区域选择性三氟甲基化反应研究，河南省教育厅高校科技创新团队(18IRTSTHN004), 2018.1-2019.12，主持
4.可见光催化体系发展醚氧原子α-位C–S键构建反应研究，中国博士后科学基金57批面上项目(2015M572110)，2015.1-2016.12，主持
5.新型含三氟甲基喹啉药物分子的合成研究，河南省科技攻关项目(172102310172)，2016.1-2017.12，主持
代表性论文：
1. Palladium-Catalyzed C–H Aminations of Anilides withN-Fluorosulfonimide
Kai Sun, Yan Li, Tao Xiong, Jingping Zhang, Qian Zhang*
J. Am. Chem. Soc.,2011,133, 1694. (ESI高被引论文)
2. Efficient Imidation of C(sp3)–H Bonds adjacent to Oxygen Atoms of Aryl Ethers under Metal-free Conditions
Kai Sun,*Xin Wang, Gang Li, Zhonghong Zhu, Yongqing Jiang, Beibei Xiao
Chem. Commun.,2014,50, 12880.
3. Copper-Catalyzed Cross-Dehydrogenative C−N Bond Formation of Azines with Azoles: Overcoming the Limitation of Oxidizing N−O Activation Strategy
Kai Sun,*Xin Wang, Lulu Liu, Jingjing Sun, Zhiguo Zhang, Guisheng Zhang*
ACS Catal.,2015,5, 7194.
4. Regioselective, Molecular Iodine-Mediated C3 Iodination of Quinolines
Kai Sun,*Yunhe Lv, Junjie Wang, Jingjing Sun, Lulu Liu, Xin Wang*
Org. Lett.,2015,17, 4408.
5. Copper-Catalyzed Arenes Amination with Saccharins
Kai Sun, Yan Li,* Qian Zhang*
Sci. China Chem.,2015,58, 1354.
6.Peroxodisulfate-Mediated Selenoamination of Alkenes yielding Amidoselenide- Ccontaining Sulfamides and Azoles
Kai Sun,*Xin Wang, Yunhe Lv, Gang Li, Hezhen Jiao, Yangyang Li, Chong Zhang, Lin Liu*
Chem. Commun.,2016,52,8471.
7. Metal-free Selenosulfonylation of Alkynes: Rapid Access toβ-(Seleno)vinyl Sulfones via a Cationic-species-induced Pathway
Kai Sun,Xin Wang, Fangfang Fu, Chong Zhang, Yao Chen, Lin Liu*
Green Chem.,2017, 19, 1490.
8. Direct Access toβ-Selenosulfones at Room Temperature through Selenosulfonylation of Alkene
Kai Sun*,Yunhe Lv, Zuodong Shi, Fangfang Fu, Chong Zhang, Zhiguo Zhang*
Sci. China Chem.,2017,60, 730.
9. Metal-free Tetra-n-butylammonium Bromide-mediated Aerobic Oxidative Synthesis ofβ-Ketosulfones from Styrenes
Xin Wan,Kai Sun*and Guisheng Zhang*
Sci. China Chem.,2017, 60, 353.
10. Aptasensors for the Selective Detection of Alpha-synuclein Oligomer by Colorimetry, Surface Plasmon Resonance and Electrochemical Impedance Spectroscopy
Kai Sun,Ning Xia, Lijuan Zhao, Ke Liu, Wenjing Hou, Lin Liu*
Senor Actuat B-Chem.,2017,245, 87.
11. Synthesis of (E)-β-Selenovinyl Sulfones through a Multicomponent Regio- and Stereospecific Selenosulfonation of Alkynes with Insertion of Sulfur Dioxide
Kai Sun,*Zuodong Shi, Zhenhua Liu, Baixue Luan, Jiali Zhu, Yanru Xue
Org. Lett.,2018,20, 6687. (ESI高被引论文)
12.Copper-Catalyzed Radical Selenodifluoromethylation of Alkenes: Access to CF2-Containingγ-Lactams
Kai Sun,*Songnan Wang, Ranran Feng, Yixiao Zhang, Xin Wang, Zhiguo Zhang,* Bing Zhang
Org. Lett.,2019,21, 2052. (ESI高被引论文)
13. C–H Imidation and Dual C–H Bond Aminobromination of Five-Membered Heterocycles
Kai Sun*,Yali Li, Ranran Feng, Shiqiang Mu, Xin Wang, Bing Zhang
J. Org. Chem.,2020,85,1001.(ESI高被引论文)
14. Electrochemically Enabled Intramolecular and Intermolecular Annulations of Alkynes
Kai Sun, *Jia Lei, Yingjie Liu, Bing Liu, Ning Chen
Adv. Synth. Catal.,2020,362, 3709. (VIP Publishing)
15. Oxidative Radical Relay Functionalization for the Synthesis of Benzimidazo[2,1-a]iso-quinolin- 6(5H)-ones
Kai Sun, *Guofeng Li, Yuyang Li, Jie Yu, Qing Zhao, Zhiguo Zhang,* Guisheng Zhang*
Adv. Synth. Catal.,2020,362, 1947.
16. An Organoselenium-Catalyzed N1- and N2-SelectiveAza-Wacker Reaction of Alkenes with Benzotriazoles
Xin Wang, Qinlin Wang, Yanru Xue,Kai Sun,*Lanlan Wu, Bing Zhang *
Chem. Commun.,2020,56, 4436.
17. Recent Advances in Tandem Selenocyclization and Tellurocyclization with Alkenes and Alkynes
Kai Sun,*Xin Wang, Chao Li, He Wang, Lei Li*
Org. Chem. Front.,2020,7, 3100 (邀稿综述).
18. Fluorination and Fluoroalkylation of Alkenes/Alkynes to Construct Fluoro-Containing Heterocycle
Xin Wang, Jia Lei, Yingjie Liu, Yong Ye, Jiazhu Li,Kai Sun*
Org. Chem. Front.,2021,8, 2079 (综述).
19. Metal-Free Organoselenium-Enabled Radical Relay Azidation–Carbocyclization
Xin Wang, Sa Guo, Yan Zhang, Zhiguo Zhang,* Guisheng Zhang,* Yong Ye,Kai Sun*
Adv. Synth. Catal.,2021,363, 3290-3296.
20. Recent Advances in the Synthetic Use of Migration Reactions of Allyl Alcohols
Yun Xing, Chen Li, Jianping Meng, Zhen Zhang, Xin Wang*, Zhichuan Wang, Yong Ye,Kai Sun*
Adv. Synth. Catal.,2021,363, 3913-3936.
21. Update on the Synthesis of N-Heterocycles via Cyclization of Hydrazones (2017–2021)
Yunhe Lv, Jianping Meng, Chen Li, Xin Wang*, Yong Ye,Kai Sun*
Adv. Synth. Catal.,2021,363, 5235-5265.
22. Radical Selenation of C(sp3)–H Bonds to Asymmetric Selenides and Mechanistic Study
Xin Wang, Jia Lei, Sa Guo, Yan Zhang, Yong Ye, Shi Tang,Kai Sun*
Chem. Commun.,2022,58, 1526-1529.
科研获奖情况：
唐敖庆化学奖学金2012年 国家研究生奖学金2013年
河南省第三届自然科学学术论文一等奖2015年
河南省第十三届“挑战杯”大学生科技作品竞赛“优秀指导教师”2017年
河南省青年骨干教师2019年
河南省教育厅科技成果一等奖2020年
